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1. Preheat oven to 350 F.
2. In medium bowl, melt semisweet chocolate and butter in microwave, stirring once.
3. Stir sugar, eggs and vanilla into chocolate mixture.
4. Stir in all-purpose flour.
5. Line muffin tin with 9 paper cupcake liners.
6. Divide batter between the 9 liners.
7. Put a teaspoon of peanut butter in the center of each.
8. Bake 20 minutes. Remove muffin tin to wire rack.
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